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Ultra-small cobalt nanoparticles from molecularly-defined Co–salen complexes for catalytic synthesis of amines

We report the synthesis of in situ generated cobalt nanoparticles from molecularly defined complexes as efficient and selective catalysts for reductive amination reactions. In the presence of ammonia and hydrogen, cobalt–salen complexes such as cobalt(ii)–N,N′-bis(salicylidene)-1,2-phenylenediamine...

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Detalles Bibliográficos
Autores principales: Senthamarai, Thirusangumurugan, Chandrashekhar, Vishwas G., Gawande, Manoj B., Kalevaru, Narayana V., Zbořil, Radek, Kamer, Paul C. J., Jagadeesh, Rajenahally V., Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157512/
https://www.ncbi.nlm.nih.gov/pubmed/34122798
http://dx.doi.org/10.1039/c9sc04963k