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Ultra-small cobalt nanoparticles from molecularly-defined Co–salen complexes for catalytic synthesis of amines
We report the synthesis of in situ generated cobalt nanoparticles from molecularly defined complexes as efficient and selective catalysts for reductive amination reactions. In the presence of ammonia and hydrogen, cobalt–salen complexes such as cobalt(ii)–N,N′-bis(salicylidene)-1,2-phenylenediamine...
Autores principales: | Senthamarai, Thirusangumurugan, Chandrashekhar, Vishwas G., Gawande, Manoj B., Kalevaru, Narayana V., Zbořil, Radek, Kamer, Paul C. J., Jagadeesh, Rajenahally V., Beller, Matthias |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157512/ https://www.ncbi.nlm.nih.gov/pubmed/34122798 http://dx.doi.org/10.1039/c9sc04963k |
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