The duality of electron localization and covalency in lanthanide and actinide metallocenes

Previous magnetic, spectroscopic, and theoretical studies of cerocene, Ce(C(8)H(8))(2), have provided evidence for non-negligible 4f-electron density on Ce and implied that charge transfer from the ligands occurs as a result of covalent bonding. Strong correlations of the localized 4f-electrons to t...

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Detalles Bibliográficos
Autores principales: Smiles, Danil E., Batista, Enrique R., Booth, Corwin H., Clark, David L., Keith, Jason M., Kozimor, Stosh A., Martin, Richard L., Minasian, Stefan G., Shuh, David K., Stieber, S. Chantal E., Tyliszczak, Tolek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157540/
https://www.ncbi.nlm.nih.gov/pubmed/34084340
http://dx.doi.org/10.1039/c9sc06114b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157540/
https://www.ncbi.nlm.nih.gov/pubmed/34084340
http://dx.doi.org/10.1039/c9sc06114b

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