Ligand-controlled cobalt-catalyzed regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes

We report a stereoselective regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes with pinacolborane (HBpin) in the presence of cobalt catalysts generated from bench-stable Co(acac)(2) and bisphosphine ligands. An interesting correlation between the regioselectivity of this hydro...

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Detalles Bibliográficos
Autores principales: Wu, Caizhi, Ge, Shaozhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157611/
https://www.ncbi.nlm.nih.gov/pubmed/34084338
http://dx.doi.org/10.1039/c9sc06136c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157611/
https://www.ncbi.nlm.nih.gov/pubmed/34084338
http://dx.doi.org/10.1039/c9sc06136c

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