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Chiral N,N′-dioxide/Mg(OTf)(2) complex-catalyzed asymmetric [2,3]-rearrangement of in situ generated ammonium salts
Catalytic enantioselective [2,3]-rearrangements of in situ generated ammonium ylides from glycine pyrazoleamides and allyl bromides were achieved by employing a chiral N,N′-dioxide/Mg(II) complex as the catalyst. This protocol provided a facile and efficient synthesis route to a series of anti-α-ami...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157646/ https://www.ncbi.nlm.nih.gov/pubmed/34122811 http://dx.doi.org/10.1039/c9sc06342k |