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Dialumenes – aryl vs. silyl stabilisation for small molecule activation and catalysis

Main group multiple bonds have proven their ability to act as transition metal mimics in the last few decades. However, catalytic application of these species is still in its infancy. Herein we report the second neutral NHC-stabilised dialumene species by use of a supporting aryl ligand (3). Differe...

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Detalles Bibliográficos
Autores principales: Weetman, Catherine, Porzelt, Amelie, Bag, Prasenjit, Hanusch, Franziska, Inoue, Shigeyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159210/
https://www.ncbi.nlm.nih.gov/pubmed/34122939
http://dx.doi.org/10.1039/d0sc01561j