Copper-catalysed photoinduced decarboxylative alkynylation: a combined experimental and computational study

Redox-active esters (RAEs) as alkyl radical precursors have demonstrated great advantages for C–C bond formation. A decarboxylative cross-coupling method is described to afford substituted alkynes from various carboxylic acids using copper catalysts CuCl and Cu(acac)(2). The photoexcitation of coppe...

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Detalles Bibliográficos
Autores principales: Mao, Yu, Zhao, Wenxuan, Lu, Shuo, Yu, Lei, Wang, Yi, Liang, Yong, Ni, Shengyang, Pan, Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159226/
https://www.ncbi.nlm.nih.gov/pubmed/34122950
http://dx.doi.org/10.1039/d0sc02213f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159226/
https://www.ncbi.nlm.nih.gov/pubmed/34122950
http://dx.doi.org/10.1039/d0sc02213f

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