Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

A cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl](+), is a precursor to efficient catalysts for the hydrosilation of alkenes with a variety of hydrosilanes under mild conditions and low catalyst loadings. DFT studies reveal the presence of...

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Detalles Bibliográficos
Autores principales: Yang, Jian, Postils, Verònica, Lipschutz, Michael I., Fasulo, Meg, Raynaud, Christophe, Clot, Eric, Eisenstein, Odile, Tilley, T. Don
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159242/
https://www.ncbi.nlm.nih.gov/pubmed/34122961
http://dx.doi.org/10.1039/d0sc00997k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159242/
https://www.ncbi.nlm.nih.gov/pubmed/34122961
http://dx.doi.org/10.1039/d0sc00997k

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