Ti-catalyzed ring-opening oxidative amination of methylenecyclopropanes with diazenes

The ring-opening oxidative amination of methylenecyclopropanes (MCPs) with diazenes catalyzed by py(3)TiCl(2)(NR) complexes is reported. This reaction selectively generates branched α-methylene imines as opposed to linear α,β-unsaturated imines, which are difficult to access via other methods. Produ...

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Detalles Bibliográficos
Autores principales: Beaumier, Evan P., Ott, Amy A., Wen, Xuelan, Davis-Gilbert, Zachary W., Wheeler, T. Alexander, Topczewski, Joseph J., Goodpaster, Jason D., Tonks, Ian A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159277/
https://www.ncbi.nlm.nih.gov/pubmed/34123005
http://dx.doi.org/10.1039/d0sc01998d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159277/
https://www.ncbi.nlm.nih.gov/pubmed/34123005
http://dx.doi.org/10.1039/d0sc01998d

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