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Ti-catalyzed ring-opening oxidative amination of methylenecyclopropanes with diazenes
The ring-opening oxidative amination of methylenecyclopropanes (MCPs) with diazenes catalyzed by py(3)TiCl(2)(NR) complexes is reported. This reaction selectively generates branched α-methylene imines as opposed to linear α,β-unsaturated imines, which are difficult to access via other methods. Produ...
Autores principales: | Beaumier, Evan P., Ott, Amy A., Wen, Xuelan, Davis-Gilbert, Zachary W., Wheeler, T. Alexander, Topczewski, Joseph J., Goodpaster, Jason D., Tonks, Ian A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159277/ https://www.ncbi.nlm.nih.gov/pubmed/34123005 http://dx.doi.org/10.1039/d0sc01998d |
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