Divergent uranium- versus phosphorus-based reduction of Me(3)SiN(3) with steric modification of phosphido ligands

We describe an example of a two-electron metal- and ligand-based reduction of Me(3)SiN(3) using uranium(iv) complexes with varying steric properties. Reaction of (C(5)Me(5))(2)U(CH(3))[P(SiMe(3))(Ph)] with Me(3)SiN(3) produces the imidophosphorane complex, (C(5)Me(5))(2)U(CH(3))[N[double bond, lengt...

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Detalles Bibliográficos
Autores principales: Ward, Robert J., Rungthanaphatsophon, Pokpong, del Rosal, Iker, Kelley, Steven P., Maron, Laurent, Walensky, Justin R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159289/
https://www.ncbi.nlm.nih.gov/pubmed/34094084
http://dx.doi.org/10.1039/d0sc02261f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159289/
https://www.ncbi.nlm.nih.gov/pubmed/34094084
http://dx.doi.org/10.1039/d0sc02261f

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