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Divergent uranium- versus phosphorus-based reduction of Me(3)SiN(3) with steric modification of phosphido ligands
We describe an example of a two-electron metal- and ligand-based reduction of Me(3)SiN(3) using uranium(iv) complexes with varying steric properties. Reaction of (C(5)Me(5))(2)U(CH(3))[P(SiMe(3))(Ph)] with Me(3)SiN(3) produces the imidophosphorane complex, (C(5)Me(5))(2)U(CH(3))[N[double bond, lengt...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159289/ https://www.ncbi.nlm.nih.gov/pubmed/34094084 http://dx.doi.org/10.1039/d0sc02261f |