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Transformations of the cyclo-P(4) ligand in [Cp′′′Co(η(4)-P(4))]
The reactivity of the cyclo-P(4) ligand complex [Cp′′′Co(η(4)-P(4))] (1) (Cp′′′ = 1,2,4-tri-tert-butyl-cyclopentadienyl) towards reduction and main group nucleophiles was investigated. By using K[CpFe(CO)(2)], a selective reduction to the dianionic complex [(Cp′′′Co)(2)(μ,η(3):η(3)-P(8))](2−) (2) wa...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159306/ https://www.ncbi.nlm.nih.gov/pubmed/34094126 http://dx.doi.org/10.1039/d0sc01740j |