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Heteroleptic actinocenes: a thorium(iv)–cyclobutadienyl–cyclooctatetraenyl–di-potassium-cyclooctatetraenyl complex
Despite the vast array of η(n)-carbocyclic C(5–8) complexes reported for actinides, cyclobutadienyl (C(4)) remain exceedingly rare, being restricted to six uranium examples. Here, overcoming the inherent challenges of installing highly reducing C(4)-ligands onto actinides when using polar starting m...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159314/ https://www.ncbi.nlm.nih.gov/pubmed/34094128 http://dx.doi.org/10.1039/d0sc02479a |