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Outer-sphere effects on ligand-field excited-state dynamics: solvent dependence of high-spin to low-spin conversion in [Fe(bpy)(3)](2+)

In condensed phase chemistry, the solvent can have a significant impact on everything from yield to product distribution to mechanism. With regard to photo-induced processes, solvent effects have been well-documented for charge-transfer states wherein the redistribution of charge subsequent to light...

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Detalles Bibliográficos
Autores principales: Miller, Jennifer N., McCusker, James K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159330/
https://www.ncbi.nlm.nih.gov/pubmed/34122975
http://dx.doi.org/10.1039/d0sc01506g