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An excited state dynamics driven reaction: wavelength-dependent photoisomerization quantum yields in [Ru(bpy)(2)(dmso)(2)](2+)

We report the excited-state behavior of a structurally simple bis-sulfoxide complex, cis-S,S-[Ru(bpy)(2)(dmso)(2)](2+), as investigated by femtosecond pump–probe spectroscopy. The results reveal that a single photon prompts phototriggered isomerization of one or both dmso ligands to yield a mixture...

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Detalles Bibliográficos
Autores principales: Livshits, Maksim Y., Wang, Lei, Vittardi, Sebastian B., Ruetzel, Stefan, King, Albert, Brixner, Tobias, Rack, Jeffrey J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159332/
https://www.ncbi.nlm.nih.gov/pubmed/34094082
http://dx.doi.org/10.1039/d0sc00551g