Ring-fused cyclobutanes via cycloisomerization of alkylidenecyclopropane acylsilanes

A novel Lewis acid-catalyzed cycloisomerization of alkylidenecyclopropane acylsilanes is disclosed. The readily available starting materials participate in tandem Prins addition/ring expansion/1,2-silyl shift to grant access to bicyclo[4.2.0]octanes and bicyclo[3.2.0]heptanes, which are common motif...

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Detalles Bibliográficos
Autores principales: Eichenberger, Sarah, Hönig, Moritz, Richter, Matthieu J. R., Gershoni-Poranne, Renana, Carreira, Erick M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159344/
https://www.ncbi.nlm.nih.gov/pubmed/34122987
http://dx.doi.org/10.1039/d0sc02224a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159344/
https://www.ncbi.nlm.nih.gov/pubmed/34122987
http://dx.doi.org/10.1039/d0sc02224a

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