Cargando…
Recent advances in N-heterocyclic carbene-based radical catalysis
In nature, a number of enzymes use thiamine diphosphate as a coenzyme to catalyze the pyruvate decarboxylation. The resultant enamine, a so-called “Breslow intermediate,” is known to perform single electron transfer to various electron acceptors. Inspired by this enzymatic catalysis, N-heterocyclic...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159350/ https://www.ncbi.nlm.nih.gov/pubmed/34094077 http://dx.doi.org/10.1039/d0sc01538e |