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Build-up of double carbohelicenes using nitroarenes: dual role of the nitro functionality as an activating and leaving group

The construction of double carbohelicenes is highly fascinating yet challenging work. Disclosed herein is a streamlined and simplified synthetic route to double carbohelicenes starting from nitroarenes through sequential nitro-activated ortho-C–H arylation, denitrative alkenylation and intramolecula...

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Detalles Bibliográficos
Autores principales: Zhou, Fulin, Zhou, Fujian, Su, Rongchuan, Yang, Yudong, You, Jingsong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159353/
https://www.ncbi.nlm.nih.gov/pubmed/34123023
http://dx.doi.org/10.1039/d0sc02058c