Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer–Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones

How far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects in the Baeyer–Villiger (BV) rearrangement by experimental and computational studies of...

Descripción completa

Detalles Bibliográficos
Autores principales: Vil', Vera A., Barsegyan, Yana A., Kuhn, Leah, Ekimova, Maria V., Semenov, Egor A., Korlyukov, Alexander A., Terent'ev, Alexander O., Alabugin, Igor V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159355/
https://www.ncbi.nlm.nih.gov/pubmed/34122989
http://dx.doi.org/10.1039/d0sc01025a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159355/
https://www.ncbi.nlm.nih.gov/pubmed/34122989
http://dx.doi.org/10.1039/d0sc01025a

Ejemplares similares