Regio- and diastereoselective reactions of chiral secondary alkylcopper reagents with propargylic phosphates: preparation of chiral allenes

The diastereoselective S(N)2′-substitution of secondary alkylcopper reagents with propargylic phosphates enables the preparation of stereodefined alkylallenes. By using enantiomerically enriched alkylcopper reagents and enantioenriched propargylic phosphates as electrophiles anti-S(N)2′-substitution...

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Detalles Bibliográficos
Autores principales: Skotnitzki, Juri, Kremsmair, Alexander, Keefer, Daniel, Schüppel, Franziska, Le Cacher de Bonneville, Brieuc, de Vivie-Riedle, Regina, Knochel, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159386/
https://www.ncbi.nlm.nih.gov/pubmed/34122991
http://dx.doi.org/10.1039/c9sc05982b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159386/
https://www.ncbi.nlm.nih.gov/pubmed/34122991
http://dx.doi.org/10.1039/c9sc05982b

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