Observations of tetrel bonding between sp(3)-carbon and THF

We report the direct observation of tetrel bonding interactions between sp(3)-carbons of the supramolecular synthon 3,3-dimethyl-tetracyanocyclopropane (1) and tetrahydrofuran in the gas and crystalline phase. The intermolecular contact is established via σ-holes and is driven mainly by electrostati...

Descripción completa

Detalles Bibliográficos
Autores principales: Heywood, Victoria L., Alford, Thomas P. J., Roeleveld, Julius J., Lekanne Deprez, Siebe J., Verhoofstad, Abraham, van der Vlugt, Jarl Ivar, Domingos, Sérgio R., Schnell, Melanie, Davis, Anthony P., Mooibroek, Tiddo J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159407/
https://www.ncbi.nlm.nih.gov/pubmed/34122986
http://dx.doi.org/10.1039/d0sc01559h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159407/
https://www.ncbi.nlm.nih.gov/pubmed/34122986
http://dx.doi.org/10.1039/d0sc01559h

Ejemplares similares