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Observations of tetrel bonding between sp(3)-carbon and THF
We report the direct observation of tetrel bonding interactions between sp(3)-carbons of the supramolecular synthon 3,3-dimethyl-tetracyanocyclopropane (1) and tetrahydrofuran in the gas and crystalline phase. The intermolecular contact is established via σ-holes and is driven mainly by electrostati...
Autores principales: | Heywood, Victoria L., Alford, Thomas P. J., Roeleveld, Julius J., Lekanne Deprez, Siebe J., Verhoofstad, Abraham, van der Vlugt, Jarl Ivar, Domingos, Sérgio R., Schnell, Melanie, Davis, Anthony P., Mooibroek, Tiddo J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159407/ https://www.ncbi.nlm.nih.gov/pubmed/34122986 http://dx.doi.org/10.1039/d0sc01559h |
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