Prediction of NHC-catalyzed chemoselective functionalizations of carbonyl compounds: a general mechanistic map

Generally, N-heterocyclic carbene (NHC) complexed with carbonyl compounds would transform into several important active intermediates, i.e., enolates, Breslow intermediates, or acylazolium intermediates, which act as either a nucleophile (Nu) or an electrophile (E) to react with the other E/Nu partn...

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Detalles Bibliográficos
Autores principales: Li, Xue, Xu, Jun, Li, Shi-Jun, Qu, Ling-Bo, Li, Zhongjun, Chi, Yonggui Robin, Wei, Donghui, Lan, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159411/
https://www.ncbi.nlm.nih.gov/pubmed/34123007
http://dx.doi.org/10.1039/d0sc01793k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159411/
https://www.ncbi.nlm.nih.gov/pubmed/34123007
http://dx.doi.org/10.1039/d0sc01793k

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