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Prediction of NHC-catalyzed chemoselective functionalizations of carbonyl compounds: a general mechanistic map
Generally, N-heterocyclic carbene (NHC) complexed with carbonyl compounds would transform into several important active intermediates, i.e., enolates, Breslow intermediates, or acylazolium intermediates, which act as either a nucleophile (Nu) or an electrophile (E) to react with the other E/Nu partn...
Autores principales: | Li, Xue, Xu, Jun, Li, Shi-Jun, Qu, Ling-Bo, Li, Zhongjun, Chi, Yonggui Robin, Wei, Donghui, Lan, Yu |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159411/ https://www.ncbi.nlm.nih.gov/pubmed/34123007 http://dx.doi.org/10.1039/d0sc01793k |
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