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Synthesis of the bis(cyclohexenone) core of (−)-lomaiviticin A

(−)-Lomaiviticin A is a complex C(2)-symmetric bacterial metabolite comprising two diazotetrahydrobenzo[b]fluorene (diazofluorene) residues and four 2,6-dideoxy glycosides, α-l-oleandrose and N,N-dimethyl-β-l-pyrrolosamine. The two halves of lomaiviticin A are linked by a single carbon–carbon bond o...

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Detalles Bibliográficos
Autores principales: Rose, John A., Mahapatra, Subham, Li, Xin, Wang, Chao, Chen, Lei, Swick, Steven M., Herzon, Seth B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159427/
https://www.ncbi.nlm.nih.gov/pubmed/34123029
http://dx.doi.org/10.1039/d0sc02770g