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What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts

Organocatalysis has revolutionized asymmetric synthesis. However, the supramolecular interactions of organocatalysts in solution are often neglected, although the formation of catalyst aggregates can have a strong impact on the catalytic reaction. For phosphoric acid based organocatalysts, we have n...

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Detalles Bibliográficos
Autores principales: Jansen, Dennis, Gramüller, Johannes, Niemeyer, Felix, Schaller, Torsten, Letzel, Matthias C., Grimme, Stefan, Zhu, Hui, Gschwind, Ruth M., Niemeyer, Jochen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159434/
https://www.ncbi.nlm.nih.gov/pubmed/34122895
http://dx.doi.org/10.1039/d0sc01026j