SET processes in Lewis acid–base reactions: the tritylation of N-heterocyclic carbenes

Reactions between N-heterocyclic carbenes (NHCs) and the trityl cation, [Ph(3)C](+), give covalent adducts of type [NHC–CPh(3)](+) and/or [NHC–C(6)H(5)–CPh(2)](+). EPR spectroscopy, UV-Vis analyses, and trapping experiments imply that adduct formation involves carbene radical cations and the trityl...

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Detalles Bibliográficos
Autores principales: Dong, Zhaowen, Pezzato, Cristian, Sienkiewicz, Andrzej, Scopelliti, Rosario, Fadaei-Tirani, Farzaneh, Severin, Kay
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159480/
https://www.ncbi.nlm.nih.gov/pubmed/34094138
http://dx.doi.org/10.1039/d0sc01278e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159480/
https://www.ncbi.nlm.nih.gov/pubmed/34094138
http://dx.doi.org/10.1039/d0sc01278e

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