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SET processes in Lewis acid–base reactions: the tritylation of N-heterocyclic carbenes
Reactions between N-heterocyclic carbenes (NHCs) and the trityl cation, [Ph(3)C](+), give covalent adducts of type [NHC–CPh(3)](+) and/or [NHC–C(6)H(5)–CPh(2)](+). EPR spectroscopy, UV-Vis analyses, and trapping experiments imply that adduct formation involves carbene radical cations and the trityl...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159480/ https://www.ncbi.nlm.nih.gov/pubmed/34094138 http://dx.doi.org/10.1039/d0sc01278e |