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Synthesis of the [11]Cyclacene Framework by Repetitive Diels–Alder Cycloadditions

The Diels–Alder cycloaddition between bisdienes and bisdienophile incorporating the 7-oxa-bicyclo[2.2.1]heptane unit are well known to show high diastereoselectivity that can be exploited for the synthesis of molecular belts. The related bisdiene 5,6,7,8-tetramethylidene-2-bicyclo[2.2.2]octene is a...

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Detalles Bibliográficos
Autores principales: Bauer, John B., Diab, Fatima, Maichle-Mössmer, Cäcilia, Schubert, Hartmut, Bettinger, Holger F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8161356/
https://www.ncbi.nlm.nih.gov/pubmed/34065279
http://dx.doi.org/10.3390/molecules26103047