Functionalized Hydroperoxide Formation from the Reaction of Methacrolein-Oxide, an Isoprene-Derived Criegee Intermediate, with Formic Acid: Experiment and Theory

Methacrolein oxide (MACR-oxide) is a four-carbon, resonance-stabilized Criegee intermediate produced from isoprene ozonolysis, yet its reactivity is not well understood. This study identifies the functionalized hydroperoxide species, 1-hydroperoxy-2-methylallyl formate (HPMAF), generated from the re...

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Detalles Bibliográficos
Autores principales: Vansco, Michael F., Zuraski, Kristen, Winiberg, Frank A. F., Au, Kendrew, Trongsiriwat, Nisalak, Walsh, Patrick J., Osborn, David L., Percival, Carl J., Klippenstein, Stephen J., Taatjes, Craig A., Lester, Marsha I., Caravan, Rebecca L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8161369/
https://www.ncbi.nlm.nih.gov/pubmed/34065491
http://dx.doi.org/10.3390/molecules26103058

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8161369/
https://www.ncbi.nlm.nih.gov/pubmed/34065491
http://dx.doi.org/10.3390/molecules26103058

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