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Deoxygenative α-alkylation and α-arylation of 1,2-dicarbonyls

Construction of C–C bonds at the α-carbon is a challenging but synthetically indispensable approach to α-branched carbonyl motifs that are widely represented among drugs, natural products, and synthetic intermediates. Here, we describe a simple approach to generation of boron enolates in the absence...

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Detalles Bibliográficos
Autores principales: Jin, Shengfei, Dang, Hang T., Haug, Graham C., Nguyen, Viet D., Arman, Hadi D., Larionov, Oleg V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8161533/
https://www.ncbi.nlm.nih.gov/pubmed/34094191
http://dx.doi.org/10.1039/d0sc03118f