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Boron tribromide as a reagent for anti-Markovnikov addition of HBr to cyclopropanes
Although radical formation from a trialkylborane is well documented, the analogous reaction mode is unknown for trihaloboranes. We have discovered the generation of bromine radicals from boron tribromide and simple proton sources, such as water or tert-butanol, under open-flask conditions. Cycloprop...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8161534/ https://www.ncbi.nlm.nih.gov/pubmed/34094209 http://dx.doi.org/10.1039/d0sc02567d |