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Reversible cooperative dihydrogen binding and transfer with a bis-phosphenium complex of chromium
The reversible reaction of H(2) with a bis-phosphenium complex of chromium provides a rare example of 3d transition metal/phosphenium cooperativity. Photolysis induces the activation of H(2) and yields a spectroscopically detectable phosphenium-stabilized (σ–H(2))-complex, readily showing exchange w...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8161683/ https://www.ncbi.nlm.nih.gov/pubmed/34094222 http://dx.doi.org/10.1039/d0sc03773g |