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Why do RuO(2) electrodes catalyze electrochemical CO(2) reduction to methanol rather than methane or perhaps neither of those?

The electrochemical CO(2) reduction reaction (CO(2)RR) on RuO(2) and RuO(2)-based electrodes has been shown experimentally to produce high yields of methanol, formic acid and/or hydrogen while methane formation is not detected. This CO(2)RR selectivity on RuO(2) is in stark contrast to copper metal...

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Detalles Bibliográficos
Autores principales: Tayyebi, Ebrahim, Hussain, Javed, Skúlason, Egill
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8161686/
https://www.ncbi.nlm.nih.gov/pubmed/34094219
http://dx.doi.org/10.1039/d0sc01882a