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Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis
The rhenium complex, [K(DME)(18-c-6)][ReH(4)(Bpin)(η(2)-HBpin)(κ(2)-H(2)Bpin)] 1, comprising hydride and boron ligands only, has been synthesized by exhaustive deoxygenation of the commercially available perrhenate anion (ReO(4)(−)) with pinacol borane (HBpin). The structure of 1 was analysed by X-r...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162066/ https://www.ncbi.nlm.nih.gov/pubmed/34094263 http://dx.doi.org/10.1039/d0sc03458d |