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Electron-driven proton transfer relieves excited-state antiaromaticity in photoexcited DNA base pairs
The Watson–Crick A·T and G·C base pairs are not only electronically complementary, but also photochemically complementary. Upon UV irradiation, DNA base pairs undergo efficient excited-state deactivation through electron driven proton transfer (EDPT), also known as proton-coupled electron transfer (...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162126/ https://www.ncbi.nlm.nih.gov/pubmed/34094268 http://dx.doi.org/10.1039/d0sc02294b |