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Formal oxo- and aza-[3 + 2] reactions of α-enaminones and quinones: a double divergent process and the roles of chiral phosphoric acid and molecular sieves

A double divergent process has been developed for the reaction of α-enaminones with quinones through facile manipulation of catalyst and additive, leading to structurally completely different products. The two divergent processes, which involve formal aza- and oxo-[3 + 2] cycloaddition reactions, ar...

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Detalles Bibliográficos
Autores principales: Luo, Weiwei, Sun, Zhicheng, Fernando, E. H. Nisala, Nesterov, Vladimir N., Cundari, Thomas R., Wang, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162164/
https://www.ncbi.nlm.nih.gov/pubmed/34094204
http://dx.doi.org/10.1039/d0sc02078h