Iron-catalyzed remote functionalization of inert C(sp(3))–H bonds of alkenes via 1,n-hydrogen-atom-transfer by C-centered radical relay

As an alternative approach to traditional C–H activation that often involved harsh conditions, and vicinal or primary C–H functionalization, radical relay offers a solution to these long-held problems. Enabled by 1,n (n = 5, 6)-hydrogen atom transfer (HAT), we use a most prevalent moiety, alkene, as...

Descripción completa

Detalles Bibliográficos
Autores principales: Bian, Kang-Jie, Li, Yan, Zhang, Kai-Fan, He, Yan, Wu, Tian-Rui, Wang, Cheng-Yu, Wang, Xi-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162260/
https://www.ncbi.nlm.nih.gov/pubmed/34123184
http://dx.doi.org/10.1039/d0sc03987j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162260/
https://www.ncbi.nlm.nih.gov/pubmed/34123184
http://dx.doi.org/10.1039/d0sc03987j

Ejemplares similares