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Iron-catalyzed remote functionalization of inert C(sp(3))–H bonds of alkenes via 1,n-hydrogen-atom-transfer by C-centered radical relay
As an alternative approach to traditional C–H activation that often involved harsh conditions, and vicinal or primary C–H functionalization, radical relay offers a solution to these long-held problems. Enabled by 1,n (n = 5, 6)-hydrogen atom transfer (HAT), we use a most prevalent moiety, alkene, as...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162260/ https://www.ncbi.nlm.nih.gov/pubmed/34123184 http://dx.doi.org/10.1039/d0sc03987j |