Regioselective addition/annulation of ferrocenyl thioamides with 1,3-diynes via a sulfur-transfer rearrangement to construct extended π-conjugated ferrocenes with luminescent properties

Herein a regioselective addition/annulation strategy of ferrocenyl (Fc) thioamides with alkynes to construct thienylferrocene (ThienylFc) structures, involving a rhodium-catalyzed C–H activation, an unusual C2-selective addition of 1,3-diyne, and an unexpected intramolecular sulfur-transfer rearrang...

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Detalles Bibliográficos
Autores principales: Yan, Lipeng, Lan, Jingbo, Cheng, Hu, Li, Yihang, Zhang, Mangang, Wu, Di, You, Jingsong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162306/
https://www.ncbi.nlm.nih.gov/pubmed/34123193
http://dx.doi.org/10.1039/d0sc04597g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162306/
https://www.ncbi.nlm.nih.gov/pubmed/34123193
http://dx.doi.org/10.1039/d0sc04597g

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