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Oxidation triggers guest dissociation during reorganization of an Fe(II)(4)L(6) twisted parallelogram

A three-dimensional Fe(II)(4)L(6) parallelogram was prepared from ferrocene-containing ditopic ligands. The steric preference of the bulky ferrocene cores towards meridional vertex coordination brought about this new structure type, in which the ferrocene units adopt three distinct conformations. Th...

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Detalles Bibliográficos
Autores principales: Plajer, Alex J., Rizzuto, Felix J., von Krbek, Larissa K. S., Gisbert, Yohan, Martínez-Agramunt, Víctor, Nitschke, Jonathan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162311/
https://www.ncbi.nlm.nih.gov/pubmed/34123180
http://dx.doi.org/10.1039/d0sc04352d