Chemically driven superstructural ordering leading to giant unit cells in unconventional clathrates Cs(8)Zn(18)Sb(28) and Cs(8)Cd(18)Sb(28)

The unconventional clathrates, Cs(8)Zn(18)Sb(28) and Cs(8)Cd(18)Sb(28), were synthesized and reinvestigated. These clathrates exhibit unique and extensive superstructural ordering of the clathrate-I structure that was not initially reported. Cs(8)Cd(18)Sb(28) orders in the Ia3̄d space group (no. 230...

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Detalles Bibliográficos
Autores principales: Owens-Baird, Bryan, Yox, Philip, Lee, Shannon, Carroll, Xian B., Grass Wang, Suyin, Chen, Yu-Sheng, Lebedev, Oleg I., Kovnir, Kirill
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162314/
https://www.ncbi.nlm.nih.gov/pubmed/34094291
http://dx.doi.org/10.1039/d0sc03846f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162314/
https://www.ncbi.nlm.nih.gov/pubmed/34094291
http://dx.doi.org/10.1039/d0sc03846f

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