Redox chemistry and H-atom abstraction reactivity of a terminal zirconium(iv) oxo compound mediated by an appended cobalt(i) center

The reactivity of the terminal zirconium(iv) oxo complex, O[triple bond, length as m-dash]Zr(MesNP(i)Pr(2))(3)CoCN(t)Bu (2), is explored, revealing unique redox activity imparted by the pendent redox active cobalt(i) center. Oxo complex 2 can be chemically reduced using Na/Hg or Ph(3)C(•) to afford...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Hongtu, Hatzis, Gillian P., Dickie, Diane A., Moore, Curtis E., Thomas, Christine M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162367/
https://www.ncbi.nlm.nih.gov/pubmed/34094325
http://dx.doi.org/10.1039/d0sc04229c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162367/
https://www.ncbi.nlm.nih.gov/pubmed/34094325
http://dx.doi.org/10.1039/d0sc04229c

Ejemplares similares