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Redox chemistry and H-atom abstraction reactivity of a terminal zirconium(iv) oxo compound mediated by an appended cobalt(i) center
The reactivity of the terminal zirconium(iv) oxo complex, O[triple bond, length as m-dash]Zr(MesNP(i)Pr(2))(3)CoCN(t)Bu (2), is explored, revealing unique redox activity imparted by the pendent redox active cobalt(i) center. Oxo complex 2 can be chemically reduced using Na/Hg or Ph(3)C(•) to afford...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162367/ https://www.ncbi.nlm.nih.gov/pubmed/34094325 http://dx.doi.org/10.1039/d0sc04229c |