H/D exchange under mild conditions in arenes and unactivated alkanes with C(6)D(6) and D(2)O using rigid, electron-rich iridium PCP pincer complexes

The synthesis and characterization of an iridium polyhydride complex (Ir-H4) supported by an electron-rich PCP framework is described. This complex readily loses molecular hydrogen allowing for rapid room temperature hydrogen isotope exchange (HIE) at the hydridic positions and the α-C–H site of the...

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Detalles Bibliográficos
Autores principales: Smith, Joel D., Durrant, George, Ess, Daniel H., Gelfand, Benjamin S., Piers, Warren E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162389/
https://www.ncbi.nlm.nih.gov/pubmed/34094323
http://dx.doi.org/10.1039/d0sc02694h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162389/
https://www.ncbi.nlm.nih.gov/pubmed/34094323
http://dx.doi.org/10.1039/d0sc02694h

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