Reversible addition of ethylene to a pincer-based boryl-iridium unit with the formation of a bridging ethylidene

This report examines reactions of a series of Ir complexes supported by the diarylboryl/bis(phosphine) PBP pincer ligand with ethylene: (PBP)IrH(4) (1), (PBP)IrH(2)(CO) (2), and (PBP)Ir(CO)(2) (3). The outcomes of these reactions differ from those typical for Ir complexes supported by other pincer l...

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Detalles Bibliográficos
Autores principales: Cao, Yihan, Shih, Wei-Chun, Bhuvanesh, Nattamai, Ozerov, Oleg V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162418/
https://www.ncbi.nlm.nih.gov/pubmed/34094348
http://dx.doi.org/10.1039/d0sc04748a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162418/
https://www.ncbi.nlm.nih.gov/pubmed/34094348
http://dx.doi.org/10.1039/d0sc04748a

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