Formation of a mixed-valence Cu(i)/Cu(ii) metal–organic framework with the full light spectrum and high selectivity of CO(2) photoreduction into CH(4)

Based upon the hetero-N,O ligand of pyrimidine-5-carboxylic acid (Hpmc), a new semiconductive Cu(i)/Cu(ii) mixed-valence MOF with the full light spectrum and a novel topology of {4(3)·6(12)·8(6)}(2){4(3)·6(3)}(2){6(3)}(6){6(4)·8(2)}(3), {(Cu(4)I(4))(2.5)[Cu(3)(μ(4)-O) (μ(3)-I) (pmc)(3)(Dabco)(3)]·2....

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Detalles Bibliográficos
Autores principales: Gao, Yajun, Zhang, Lei, Gu, Yuming, Zhang, Wenwei, Pan, Yi, Fang, Weihai, Ma, Jing, Lan, Ya-Qian, Bai, Junfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162430/
https://www.ncbi.nlm.nih.gov/pubmed/34094277
http://dx.doi.org/10.1039/d0sc03754k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162430/
https://www.ncbi.nlm.nih.gov/pubmed/34094277
http://dx.doi.org/10.1039/d0sc03754k

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