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Formation of a mixed-valence Cu(i)/Cu(ii) metal–organic framework with the full light spectrum and high selectivity of CO(2) photoreduction into CH(4)
Based upon the hetero-N,O ligand of pyrimidine-5-carboxylic acid (Hpmc), a new semiconductive Cu(i)/Cu(ii) mixed-valence MOF with the full light spectrum and a novel topology of {4(3)·6(12)·8(6)}(2){4(3)·6(3)}(2){6(3)}(6){6(4)·8(2)}(3), {(Cu(4)I(4))(2.5)[Cu(3)(μ(4)-O) (μ(3)-I) (pmc)(3)(Dabco)(3)]·2....
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162430/ https://www.ncbi.nlm.nih.gov/pubmed/34094277 http://dx.doi.org/10.1039/d0sc03754k |