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Anodic oxidation triggered divergent 1,2- and 1,4-group transfer reactions of β-hydroxycarboxylic acids enabled by electrochemical regulation

We report a set of electrochemically regulated protocols for the divergent synthesis of ketones and β-keto esters from the same β-hydroxycarboxylic acid starting materials. Enabled by electrochemical control, the anodic oxidation of carboxylic acids proceeded in either a one-electron or a two-electr...

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Detalles Bibliográficos
Autores principales: Zhang, Zhenxing, Zhang, Lei, Zhang, Xianhao, Yang, Jianxin, Yin, Yunxing, Jiang, Yangye, Zeng, Chengchu, Lu, Gang, Yang, Yang, Mo, Fanyang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162457/
https://www.ncbi.nlm.nih.gov/pubmed/34123217
http://dx.doi.org/10.1039/d0sc02386h